Prof. W. Grimme
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Publikationen

1999

    Galasso, V., Grimme, W., Lex, J., Jones, D., Modelli, A.
    A study of the molecular structure and spectroscopic properties of tetrahydro[4]beltene and related compounds.
    Chem Phys, 1999, 242, 203.

1998

    Grimme, W., Wortmann, J., Frowein, D., Lex, J., Chen, G., Gleiter, R.
    Laticyclic conjugated double bonds within the framework of oligocondensed bicyclo[2.2.2]octenes.
    J Chem Soc Perkin Trans 2, 1998, 1893.
    Grimme, W., Bertsch, A., Flock, H., Noack, T., Krauthäuser, S.
    Bridged Medium Rings with Hyperstable Double Bonds - Syntheses and Reactions.
    Synlett, 1998, 1175.
    Grimme, W., Gossel, J., Lex, J.
    Tetrachlor-p-(o,p)-o-tribenzol als Baustein für Diels-Alder-Oligomere von Benzol und für ein laticyclisch konjugiertes Hexaen.
    Angew Chem, 1998, 110, 479; Angew Chem , Int Ed Engl, 1998, 37, 473.

1997

    Grimme, W., Geich, H., Lex, J., Heinze, J.
    Hexacycl[8.7.0.0(3,8).0(5,15).0(6,13).0(12,16)]-heptadeca-1(10),5-diene-3,8-dicarboxylic Anhydride, a Tetrahydro(4)Beltene with 2 Sigma Conjugated Double Bonds.
    J Chem Soc Perkin Trans 2, 1997, 1955.
    Grimme, W., Krauthäuser, S.
    Degenerate Cope Rearrangement of Tetracyclo[7.3.1.0(2,8).0(4,12)]trideca-5,10-diene.
    Tetrahedron, 1997, 53, 9903.

1996

    Grimme, W., Pohl, K., Wortmann, J., Frowein, D.
    Dyotrope Wasserstoffübertragung in Dihydrosesqui- und in Dihydro-syn-sesterbicyclo[2.2.2]octenen.
    Liebigs Ann, 1996, 1905.

1993

    Engelhardt, T.P., Belkoura, L., Woermann, D., Grimme, W.
    Dynamic light scattering experiments with aqueous solutions of a cascade molecule: benzene[9]3-arborol.
    Ber Bunsen-Ges Phys Chem, 1993, 97, 33.

1992

    Geich, H., Grimme, W., Proske, K.
    Dyotropic (6 + 4)-hydrogen migration in a 2,3-bis(methylene)decahydro-anthracene.
    J Am Chem Soc, 1992, 114, 1492.
    Grimme, W., Grommes, T., Roth, W.R., Breuckmann, R.
    The benzene ring as dienophile in an intramolecular (4 + 2)-cycloaddition: The degenerate rearrangement of 7,8-benzobicyclo[4.2.2]deca-2,4,7,9-tetraene.
    Angew Chem, 1992, 104, 867; Angew Chem , Int Ed Engl, 1992, 31, 872.

1991

    Grimme, W., Kaemmerling, H.T., Lex, J., Gleiter, R., Heinze, J., Dietrich, M.
    syn-Sesqui- and sesterbenzobicyclo[2.2.2]octenes. Molecules with stacked benzene rings.
    Angew Chem, 1991, 103, 215; Angew Chem , Int Ed Engl, 1991, 30, 205.

1989

    Grimme, W., Hoener, P., Kaemmerling, H.T., Waldraff, R., Wirz, J.
    Diels-Alder adducts of side b of naphthalene. Rapid decomposition of o-quinodimethane derivatives.
    Angew Chem, 1989, 101, 1390 ; Angew Chem , Int Ed Engl, 1989, 28, 1353.

1988

    Bertsch, A., Grimme, W., Reinhardt, G., Rose, H., Warner, P.M.
    Homoaromatic delocalization in the transition state for norcaradiene formation.
    J Am Chem Soc, 1988, 110, 5112.
    Grimme, W., Wiechers, G.
    Sequential thermal rearrangements of syn-9-vinylbicyclo[6.1.0]- nona-2,4,6-triene.
    Tetrahedron Lett, 1988, 29, 5249.

1987

    Grimme, W., Lex, J., Schmidt, T.
    Electrocyclic cleavage of 2,3-benzo- and 2,3;7,8-dibenzo-bicyclo[4.2.0]octa-2,4,7-triene: benzanellated transition state.
    Angew Chem, 1987, 99, 1277.
    Grimme, W., Wiechers, G.
    Intramolecular Diels-Alder reaction of bicyclo[6.4.0]dodeca-4,9,11-triene.
    Tetrahedron Lett, 1987, 28, 6035.

1986

    Bertsch, A., Grimme, W., Reinhardt, G.
    Diels-Alder-Addukte von Benzol an Arene und ihre (4 + 2)-Cycloreversion.
    Angew Chem, 1986, 98, 361.

1985

    Grimme, W., Mauer, W., Sarter, C.
    Intramolecular (4 + 2)-cycloreversion of two symmetric homobasketenes.
    Angew Chem, 1985, 97, 354.

1983

    Grimme, W., Reinhardt, G.
    p-(o,p)-o-Tribenzene and p-(o,p)-(o,o)-p-Tetrabenzene, Diels-Alder oligomers of benzene.
    Angew Chem, 1983, 95, 636; Angew Chem , Int Ed Engl, 1983, 22, 617.
    Roth, W.R., Klaerner, F.G., Grimme, W., Koeser, H.G., Busch, R., Muskulus, B., Breuckmann, R., Scholz, B.P., Lennartz, H.W.
    Stereochemistry of the bicyclo[2.1.0]pentane ring opening; thermolysis of tricyclo[3.2.0.0(2,4)]heptane derivatives.
    Chem Ber, 1983, 116, 2717.

1982

    Pritschins, W., Grimme, W.
    9,10-Dewar anthracene.
    Tetrahedron Lett, 1982, 23, 1151
    Huber, W., Muellen, K., Busch, R., Grimme, W., Heinze, J.
    A bishomocyclooctatetraene dianion.
    Angew Chem, 1982, 94, 294.

1981

    Alder, R.W., Grimme, W.
    Bond-making in the 1,5-sigmatropic migration of unsaturated groups.
    Tetrahedron, 1981, 37, 1809.
    Gleiter, R., Gubernator, K., Grimme, W.
    Evidence for a strong through-bond interaction in anti-tricyclo[6.4.0.0(2,7)]dodecatetraene.
    J Org Chem, 1981, 46, 1247.
    Grimme, W., Koeser, H.G.
    syn- and anti-Norcaradieneiron tricarbonyl.
    J Am Chem Soc, 1981, 103, 5919.
    Grimme, W., Schumachers, L., Gleiter, R., Gubernator, K.
    anti-(4 + 4)-Dicyclopentadiene.
    Angew Chem, 1981, 93, 98.
    Grimme, W., Schumachers, L., Roth, W.R., Breuckmann, R.
    anti-(4 + 4)-Dicyclopentadiene.
    Chem Ber, 1981, 114, 3197.

1980

    Grimme, W., Koeser, H.G.
    9,10-Benzotricyclo[6.2.2.0(2,7)]dodeca-3,5,9,11-tetraene, a Diels-Alder adduct from benzene and naphthalene. Angew Chem, 1980, 92, 307; Angew Chem , Int Ed Engl, 1980, 19, 307.
      Papies, O., Grimme, W.
      Acceleration of the (4 + 2)-cycloreversion by the alkoxide substituent.
      Tetrahedron Lett, 1980, 21, 2799.

    1979

      Ashkenazi, P., Kaftory, M., Grimme, W., Heger, K., Vogel, E., Ginsburg, D.
      Propellanes. LIV. Reactions of [4.4.1], [4.3.1] and [4.2.1]propella-2,4-dienes with 4-substituted-1,2,4-triazoline- 3,5-diones.
      Bull Soc Chim Belg, 1979, 88, 841.
      Grimme, W., Mauer, W., Reinhardt, G.
      Tricyclo[4.2.2.1(2,5)]undeca-3,7,9-triene, the (4 + 4)-cycloadduct from benzene and cyclopentadiene, and the reaction sequence of its reverse cleavage.
      Angew Chem, 1979, 91, 254.
      Pritschins, W., Grimme, W.
      1,2,3,4-Tetrachloro-9,10-Dewar-anthracene.
      Tetrahedron Lett, 1979, 4545.

    1978

      Frank, J., Grimme, W., Lex, J.
      1,6-Dimethylbicyclo[4.4.1]undeca-2,4,7,9-tetraene, a higher vinylog of norbornadiene.
      Angew Chem, 1978, 90, 1002.
      Grimme, W., Heinze, U.
      Kinetics and enthalpy of isomerization of benzobicyclo[2.2.0]hexa-2,5-diene.
      Chem Ber, 1978, 111, 2563.
      Neukam, W., Grimme, W.
      Anionic (4 + 2)-cycloreversions leading to the cyanocyclopentadienide ion.
      Tetrahedron Lett, 1978, 2201.

    1977

      Grimme, W., Schneider, E.
      3-6-h-Tricyclo[6.2.2.0(2,7)]dodeca-3,5,9,11-tetraene-tricarbonyliron, a stable transition metal complex of o,p'- dibenzene.
      Angew Chem, 1977, 89, 754; Angew Chem , Int Ed Engl, 1977, 16, 717.

    1976

      Heger, K., Grimme, W.
      Degenerate butadienylcyclopropane rearrangement in tricyclo[5.3.0.0(2,10)]deca-3,5-diene.
      Angew Chem, 1976, 88, 62; Angew Chem , Int Ed Engl, 1976, 15, 53.
      Mauer, W., Grimme, W.
      Two consecutive cycloreversions of as-homobasketene (pentacyclo[5.4.0.0(2,5).0(3,9).0(4,8)]undecene-10). Tetrahedron Lett, 1976, 1835.

    1975

      Guenther, H., Pawliczek, J.B., Ulmen, J., Grimme, W.
      Proton resonance spectroscopy of unsaturated ring systems. XXIII. Cope rearrangement of 3,4-homotropilidene. Chem Ber, 1975, 108, 3141.

    1974

      Klein, H., Grimme, W.
      4,8-Dioxabicyclo[5.1.0]octa-2,5-diene.
      Angew Chem, 1974, 86, 742; Angew Chem , Int Ed Engl, 1974, 13, 672.

    1973

      Grimme, W.
      Thermal rearrangement of cis-bicyclo[6.1.0]nona-2,6-dienes.
      J Amer Chem Soc, 1973, 95, 2381.
      Grimme, W., Rother, H.J.
      Diradicalic 2,3-dimethylene-1,4-cyclohexadiyl intermediate of thermal rearrangements in the gas phase.
      Angew Chem, 1973, 85, 512.
      Grimme, W., Seel, K.
      Cope rearrangement of cis-bicyclo[6.1.0]nona-2,6-diene and its 9-hetero analogs.
      Angew Chem, 1973, 85, 514.
      Grimme, W., von Eggers Doering, W.
      Degenerate butadienylcyclopropane rearrangement in bicyclo[5.1.0]octa-2,4-diene.
      Chem Ber, 1973, 106, 1765.
      Klein, H., Kursawa, W., Grimme, W.
      Rapid reversible Cope rearrangement of s-oxabicyclo[5.1.0]octa-2,5-dienes.
      Angew Chem, 1973, 85, 624; Angew Chem , Int Ed Engl, 1973, 12, 580.

    1972

      Grimme, W.
      cis-Bicyclo[6.2.0]deca-2,6-diene.
      J Amer Chem Soc, 1972, 94, 2525
      Guenther, H., Pawliczek, J.B., Ulmen, J., Grimme, W.
      Kinetics of the homotropilidene valence tautomerism.
      Angew Chem, 1972, 84, 536; Angew Chem , Int Ed Engl, 1972, 11, 517.

    1970

      Bleck, W. E., Grimme, W., Guenther, H., Vogel, E.
      Tricyclo[4.3.1.0(1,6)]deca-2,4-diene-tricarbonylchromium, a homoaromatic transition metal complex.
      Angew Chem , Int Ed Engl, 1970, 9, 303.
      Grimme, W., Reisdorff, J., Jünemann, W., Vogel, E.
      4,9-Methano[11]annulenone. A ten-p-electron analog of tropone.
      J Amer Chem Soc, 1970, 92, 2525.

    1969

      Guenther, H., Wenzl, R., Grimme, W.
      Proton magnetic resonance spectroscopy of unsaturated ring systems. XI. Chromium tricarbonyl complexes of cycloheptatriene and 1,6-methano[10]annulene.
      J Amer Chem Soc, 1969, 91, 3808.

    1968

      Vogel, E., Korte, S., Grimme, W., Guenther, H.
      1,1-Difluorobenzocyclopropene.
      Angew. Chem. 1968, 80, 279; Angew Chem , Int Ed Engl, 1968, 7, 289.
      Grimme, W., Riebel, H. J., Vogel, E.
      Degenerierte thermische Valenzisomerisierung des Bicyclo[4.2.2]deca-2,4,7,9-tetraen-Gerüstes.
      Angew. Chem. 1968, 80, 803.

    1967

      Grimme, W.
      Thermal rearrangement of cis-bicyclo[6.1.0]nona-2,4,6-triene-molybdenum-tricarbonyl.
      Chem Ber, 1967, 100, 113.
      Lehmkuhl, H., Grimme, W.
      Organometallic compounds. XLIV. Electrochemical studies on the synthesis of ethyl metal compounds.
      Justus Liebigs Ann Chem, 1967, 705, 1.
      Grimme, W., Heilbronner, E., Hohlneicher, G., Vogel, E., Weber, J. P.
      Die Elektronenzustände von Perimeter-p-Systemen: Das Elektronenspektrum des 1,6-Methano[11annulenium- Kations.
      Helv Chim Acta 1967, 51, 225.

    1966

      Roth, W. R., Grimme, W.
      Wasserstoffverschiebung im Cycloheptatrien-molybdän-tricarbonyl.
      Tetrahedron Lett, 1966, 2347.
      Fischer, E. O., Rühle, H., Vogel, E., Grimme, W.
      1,6-Methanocyclodecapentaen-chrom-tricarbonyl.
      Angew. Chem. 1966, 78, 548.
      Günther, H., Grimme, W.
      Zur Struktur des Tricarbonyl-1,6-methano-cyclodecapentaen-chroms.
      Angew. Chem. 1966, 78, 1063.
      Grimme, W., Kaufhold, M., Dettmeier, U., Vogel, E.
      Tricyclo[4.3.1.0(1,6)]deca-2,4,7-trien, ein acider alicyclischer Kohlenwasserstoff.
      Angew. Chem. 1966, 78, 643.
      Vogel, E., Grimme, W., Meckel, W., Riebel, H. J., Oth, J. F. M.
      Eine neue Synthese des Bullvalen-Systems.
      Angew. Chem. 1966, 78, 599.

    1965

      Grimme, W.
      Reversible thermische Umlagerung von Bicyclo[5.1.0]octen-(2) in Cyclooctadien-(1,4).
      Chem Ber, 1965, 98, 756.
      Vogel, E., Grimme, W., Dinné, E.
      Ein Beitrag zur Stereochemie der Valenzisomerisierung von Trienen mit zentraler cis-Doppelbindung zu Cyclohexa-1-3-dienen.
      Tetrahedron Lett, 1965, 391.
      Vogel, E., Grimme, W., Korte, S.
      Benzocyclopropen.
      Tetrahedron Lett, 1965, 3625.
      Grimme, W., Hoffmann, H., Vogel, E.
      Synthese des Bicyclo[5.4.1]dodecapentaenylium Ions, eines Carboniumions mit 10 p-Electronen.
      Angew. Chem. 1965, 77, 348.

    1964

      Vogel, E., Meckel, W., Grimme, W.
      Versuche zur Synthese von Cyclodecapentaenen durch Valenzisomerisierung von 9,10-Dihydronaphthalinen. Angew. Chem. 1964, 76, 786.